Tunneling in the condensed phase : barrier crossing and dynamical control
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4 Dispersive kinetics
Chemical reactions proceeding on time-scales comparable to or shorter than those of internal rearrangements in the reaction system renewing the environment of reactants (mixing) are, in general, dispersive. For dispersive kinetics, as for dispersive transport and dispersive relaxation, many time-scales coexist, and the rate coefficients, termed the specific reaction rates, depend on time. In cl...
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